Structure-Reactivity Correlations of Excited States of Perfluorinated Compounds: A Time Resolved Raman Study | Zendy

R. Anandhi | Zendy; Gurusamy Balakrishnan | Zendy; P. Mohandas | Zendy; Siva Umapathy | Zendy

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Structure-Reactivity Correlations of Excited States of Perfluorinated Compounds: A Time Resolved Raman Study

Author(s) -

R. Anandhi,

Gurusamy Balakrishnan,

P. Mohandas,

Siva Umapathy

Publication year - 1999

Publication title -

laser chemistry

Language(s) - English

Resource type - Journals

eISSN - 1026-8014

pISSN - 0278-6273

DOI - 10.1155/1999/68497

Subject(s) - excited state , chemistry , raman spectroscopy , reactivity (psychology) , excitation , photochemistry , ground state , computational chemistry , atomic physics , physics , optics , quantum mechanics , medicine , alternative medicine , pathology

This paper reports the TR3 spectral studies on perfluorinated organic systems with the objective to understand the influence of perfluorination on the excited states. We have recorded the TR3 spectra and Raman excitation profiles of the triplet excited states of decafluorobenzophenone and fluoranil. It is found that the influence of perfluorination is more pronounced in the triplet excited state than the ground state and thus leads to enhanced reactivity for perfluorinated compounds through larger structural distortions.

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