Time-Resolved, Step-Scan Ftir Studies Of Excited States Of d6 Metal Polypyridine Complexes
Author(s) -
Jon R. Schoonover
Publication year - 1999
Publication title -
laser chemistry
Language(s) - English
Resource type - Journals
eISSN - 1026-8014
pISSN - 0278-6273
DOI - 10.1155/1999/36437
Subject(s) - chemistry , microsecond , excited state , fourier transform infrared spectroscopy , excitation , spectroscopy , transient (computer programming) , laser , metal , fourier transform , infrared , ultrafast laser spectroscopy , photochemistry , atomic physics , optics , organic chemistry , mathematical analysis , physics , electrical engineering , mathematics , quantum mechanics , computer science , engineering , operating system
Time-resolved infrared spectroscopy using step-scan FTIR has been developed as anapproach to study transient inorganic species with lifetimes ranging from ca. 200nanseconds to several microseconds. This approach has been applied to a variety ofproblems arising following laser excitation of d 6 polypyridine complexes in solution, andseveral examples are shown to demonstrate the utility of this experiment.
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