Hydrophobicity of Water at the Surface as Studied by laser-Induced Fluorescence Microscopy
Author(s) -
Yao-qun Li,
Shinya Sasaki,
Takanori Inoue,
Teiichiro Ogawa
Publication year - 1998
Publication title -
laser chemistry
Language(s) - English
Resource type - Journals
eISSN - 1026-8014
pISSN - 0278-6273
DOI - 10.1155/1998/57838
Subject(s) - chromophore , fluorescence , chemistry , fluorescence microscope , surface water , photochemistry , polar , microscopy , hydrocarbon , air water , surface (topology) , chemical engineering , analytical chemistry (journal) , chromatography , optics , organic chemistry , environmental engineering , physics , geometry , mathematics , astronomy , mechanics , engineering
A sensitive comparative fluorescence microscopic approach was developed and used to study the water at the air-water interface region. An insoluble chromophore meso-alpha, beta, gamma, delta-tetraphenylporphine (TPP) was spread on the water. Its fluorescence spectrum indicated that the spectrum of TPP on the water surface was similar to those measured in nonpolar hydrocarbon solvents. Thus, the water at the surface was concluded to be hydrophobic and less polar than the water in the bulk
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