Formation of the State‐Selected CH Radical Beam and its Application to The CH + NO Reaction | Zendy

Makoto Takezaki | Zendy; H. Ohoyama | Zendy; Toshio Kasai | Zendy; Keigi Kuwata | Zendy

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Formation of the State‐Selected CH Radical Beam and its Application to The CH + NO Reaction

Author(s) -

Makoto Takezaki,

H. Ohoyama,

Toshio Kasai,

Keigi Kuwata

Publication year - 1995

Publication title -

laser chemistry

Language(s) - English

Resource type - Journals

eISSN - 1026-8014

pISSN - 0278-6273

DOI - 10.1155/1995/97838

Subject(s) - chemistry , state (computer science) , beam (structure) , photochemistry , optics , algorithm , computer science , physics

The CH(X2II) radical beam was produced via the decomposition of methanol by a dc-discharge in a pulsed supersonic beam. The CH radical beam was rotationally state-selected and separated from other discharge products by using an electrostatic hexapole field. The chemiluminescence from the reaction of CH in the |3/2, 3/2, 3/2> state with NO was measured under the crossed beam condition. The wavelength region of the present chemiluminescence confirms no NH(A3II) formation. The formation of HCN(X) and/or OH(X2II) is tentatively proposed.

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