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Absolute rate constants for HO 2  + NO and NH 2  + NO reactions were measured by a photoionizationmass spectrometry coupled with a laser flash photolysis. HO 2  and NH 2  radicals were photoionized byan Ar resonance lamp and were detected as their parent ions (   HO  2  +    and    NH  2  +   ). The rate constants weredetermined to be    K   (HO   2      +     NO   )   =   (   6.5        ±     2.0   )        10    −  12cm   3molecule    −  1s   −  1K   (NH   2      +     NO   )   =   (   1.9        ±     0.3   )        10    −  11cm   3molecule    −  1s   −  1Both rates are consistent with those previously reported.

Measurements of Rate Constants for HO2 + NO and NH2 + NO Reactions by Time-Resolved Photoionization Mass Spectrometry

Measurements of Rate Constants for HO₂ + NO and NH₂ + NO Reactions by Time-Resolved Photoionization Mass Spectrometry