The Spectroscopy and Photophysics of π Hydrogen‐BondedComplexes: Benzene–CHCl3 | Zendy

Albert J. Gotch | Zendy; R. N. Pribble | Zendy; Frederick A. Ensminger | Zendy; Timothy S. Zwier | Zendy

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The Spectroscopy and Photophysics of π Hydrogen‐BondedComplexes: Benzene–CHCl₃

Author(s) -

Albert J. Gotch,

R. N. Pribble,

Frederick A. Ensminger,

Timothy S. Zwier

Publication year - 1994

Publication title -

laser chemistry

Language(s) - English

Resource type - Journals

eISSN - 1026-8014

pISSN - 0278-6273

DOI - 10.1155/1994/41604

Subject(s) - chemistry , benzene , spectroscopy , photochemistry , hydrogen , organic chemistry , physics , quantum mechanics

A vibronic level study of the spectroscopy and photophysics of the C6H6–CHCl3 complex has been carried out using a combination of laser-induced fluorescence and resonant two-photon ionization (R2PI). In C6H6-CHCl3, the S1–S0 origin remains forbidden while the 1610 transition is weakly induced. Neither 610 nor 1610 are split by the presence of the CHCl3 molecule. On this basis, a C3vstructure is deduced for the complex, placing CHCl3 on the six-fold axis of benzene. The large blue-shift of the complex’s absorption relative to benzene (

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