The Vibrational-Translational Relaxation of CF2HCl in Argon | Zendy

V. Toşa | Zendy; R. Bruzzese | Zendy; C. de Lisio | Zendy; D. Tescione | Zendy

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The Vibrational-Translational Relaxation of CF₂HCl in Argon

Author(s) -

V. Toşa,

R. Bruzzese,

C. de Lisio,

D. Tescione

Publication year - 1994

Publication title -

laser chemistry

Language(s) - English

Resource type - Journals

eISSN - 1026-8014

pISSN - 0278-6273

DOI - 10.1155/1994/35971

Subject(s) - chemistry , vibrational energy relaxation , translational energy , excitation , argon , relaxation (psychology) , atomic physics , vibrational energy , buffer gas , laser , analytical chemistry (journal) , molecule , optics , physics , psychology , social psychology , organic chemistry , chromatography , quantum mechanics , dissociation (chemistry)

We report in this paper results concerning the vibrational-translational (VT) rates of CF2HCl diluted in Ar as a neutral buffer. The dependence on the buffer concentration and on the initial vibrational energy distribution are obtained by using the 9R(48) and the 9R(34) CO, laser lines for the excitation process. The differences observed between the results corresponding to the two lines bear valuable information about the dependence of the VT relaxation process on the specific initial conditions of vibrational excitation

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