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The chemiluminescence of BaO in the range 600-800 nm has been observed for the first time in thereaction between Ba   (  6  s  6   p  1    P  1   )    andCO   2in a crossed beam experiment under single collision conditions.The observed spectrum is attributed to the emission from theA  1    Σ  +state of BaO and no emission from the    A   '1    Π    is visible under our experimental conditions. The distribution of lowν  'in theA  1    Σ  +state appearsstatistical at low collision energy and, at higher collision energy, theν  '   =  1    appears less populated thanstatistically predicted.

laser chemistry

Chemiluminescent Emission in the Reaction <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:mtext>Ba</mml:mtext><mml:mo stretchy="false">(</mml:mo><mml:mn>6</mml:mn><mml:mtext>s</mml:mtext><mml:mn>6</mml:mn><mml:msup><mml:mtext>p</mml:mtext><mml:mn>1</mml:mn></mml:msup><mml:msub><mml:mtext>P</mml:mtext><mml:mn>1</mml:mn></mml:msub><mml:mo stretchy="false">)</mml:mo><mml:mo>+</mml:mo><mml:msub><mml:mrow><mml:mtext>CO</mml:mtext></mml:mrow><mml:mn>2</mml:mn></mml:msub><mml:…

Chemiluminescent Emission in the Reaction Ba(6s6p1P1)+CO2