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The vibrational (and rotational) energy distribution ofN  2  +   (X)    ionsproduced in theHe   +   /   N  2   O    charge transfer reaction at thermalenergy has been measured by laser induced fluorescence usingan Ion Cyclotron Resonance cell to store the ions. Vibrationallevels up toV  "   =  5    have been observed.  The relaxation processes experienced by theN  2  +(X) ions beforelaser detection are discussed.

laser chemistry

Laser Induced Fluorescence of <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msubsup><mml:mtext>N</mml:mtext><mml:mtext>2</mml:mtext><mml:mtext>+</mml:mtext></mml:msubsup><mml:mo stretchy="false">(</mml:mo><mml:mtext>X,v</mml:mtext><mml:mo>"</mml:mo><mml:mo stretchy="false">)</mml:mo></mml:mrow></mml:math> Resulting From the Thermal Energy Dissociative Charge Transfer Reaction <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msup><mml:mrow><mml:…

Laser Induced Fluorescence of N2+(X,v") Resulting From the Thermal Energy Dissociative Charge Transfer Reaction