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Collisions that produce a change in the total angular-momentum and quenching processes involving thetripletZ  3    F  0titanium excited level and diatomic molecules have been studied by laser perturbation andtime-resolved spectroscopy. The thermally averaged total angular-momentum changing cross sections    (    z  3    F  i  0   →   z  3    F  j  0    )in units of10    −  16cm   2      are:       σ  ¯    42    =  3.2  ±  1  ,     1.4  ±  0.5  ;       σ  ¯    43    =  13.3  ±  2  ,     6.8  ±  1  ;       σ  ¯    32       =  19.0  ±  2  ,     7.2  ±  1   , respectively, for nitrogen and hydrogen colliding partners.  Large quenching cross sections are obtained, asσ  −    Q    N  2=  53  ±  7   , andσ  −    Q    H  2=  38  ±  4    in units of 10 -16  cm 2 .These results are discussed in relation with previous measurements dealing with titanium-noble-gascollisions, and with available published results.

laser chemistry

Change In Total Angular Momentum Within The <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msup><mml:mi>Z</mml:mi><mml:mn>3</mml:mn></mml:msup><mml:msup><mml:mi>F</mml:mi><mml:mn>0</mml:mn></mml:msup></mml:mrow></mml:math> Titanium Excited State Induced By Collisions With Hydrogen And Nitrogen Molecules

Change In Total Angular Momentum Within The Z3F0 Titanium Excited State Induced By Collisions With Hydrogen And Nitrogen Molecules