Partitioning of Transuranic Metal Ions to Ionic Liquids Containing the Ionizable Complexant Cyanex-272 | Zendy

Violina Cocalia | Zendy

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Partitioning of Transuranic Metal Ions to Ionic Liquids Containing the Ionizable Complexant Cyanex-272

Author(s) -

Violina Cocalia

Publication year - 2004

Publication title -

ecs proceedings volumes

Language(s) - English

Resource type - Journals

eISSN - 2576-1579

pISSN - 0161-6374

DOI - 10.1149/200424.0779pv

Subject(s) - ionic liquid , americium , chemistry , inorganic chemistry , aqueous solution , extraction (chemistry) , coordination number , metal , solvent , coordination complex , ion , metal ions in aqueous solution , extended x ray absorption fine structure , ionic bonding , imide , absorption spectroscopy , actinide , polymer chemistry , organic chemistry , physics , quantum mechanics , catalysis

Extraction mechanisms in Ionic Liquid (IL) based separations systems for metal ions are potentially much more complex that those with simple organic solvents as extracting phases. This arises from the potential for either, or, both cations and anions from the IL to contribute in the extraction processes. In contrast to organic extracting phases, ionic liquids can not necessarily be considered to be passive carrier fluids. Solvent extraction and cation, anion, or sacrificial ion exchange mechanisms have been observed, and the significance of each varies depending on the nature of the ionic liquid components and of the complexants used. Recognition and application of this knowledge allows potential control of the complexation and extraction mechanisms.

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