A Thermodynamic Database for AlCl3-Based Molten Salt Systems | Zendy

Christian Robelin | Zendy

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A Thermodynamic Database for AlCl3-Based Molten Salt Systems

Author(s) -

Christian Robelin

Publication year - 2004

Publication title -

ecs proceedings volumes

Language(s) - English

Resource type - Journals

eISSN - 2576-1579

pISSN - 0161-6374

DOI - 10.1149/200424.0108pv

Subject(s) - phase diagram , thermodynamics , gibbs free energy , ternary operation , enthalpy , stoichiometry , vapor pressure , thermodynamic databases for pure substances , chemistry , mixing (physics) , molten salt , binary number , phase (matter) , thermodynamic process , material properties , computer science , physics , arithmetic , mathematics , organic chemistry , quantum mechanics , programming language

Chloroaluminate melts can be used as electrolytes for the production of aluminum and they are also involved in high energy density batteries (“Zebra” battery) : Na/βAl2O3/NaAlCl4, FeCl2, Fe. Molten chlorides have many other industrial applications. For example, transitionmetal chlorides are involved in the hot corrosion of metallic alloys. They are also used in the production of magnesium by electrolysis : the electrolyte is NaCl-KClMgCl2-CaCl2 and the transition-metal chlorides (mostly MnCl2 and FeCl2) are dissolved impurities.

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