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The performance of copper-plated, stainless-steel plates, having an active area of 2.5x2.5 cm 2 square, was tested for use with an SOFC having a Cu-based anode for direct oxidation of n-butane at 973 K. In the absence of Cu, catastrophic carbon deposition, which rapidly caused blocking of the fuel channels, was observed due to reaction of the n-butane on the stainless steel. However, plating the fuel channels with Cu effectively prevented formation of large carbon deposits. After 24 hr operation in pure n-butane, the Cu plating effectively suppressed carbon deposition, except for the formation of tar-like substances formed by gas-phase thermal decomposition of the hydrocarbon. The tar-like substances were found to be soluble in toluene and could be analyzed by GC/MS, which showed that they were primarily poly-aromatic hydrocarbons having 2-6 aromatic rings.

Copper-Plated Stainless Steel for Bipolar Plates in Direct-Oxidation SOFC