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Rates of Adsorption, Desorption, and Oxidation of CO on PEM Electrodes
Author(s) -
Balasubramanian Lakshmanan
Publication year - 2002
Publication title -
ecs proceedings volumes
Language(s) - English
Resource type - Journals
eISSN - 2576-1579
pISSN - 0161-6374
DOI - 10.1149/200231.0149pv
Subject(s) - desorption , adsorption , chemistry , proton exchange membrane fuel cell , diffusion , analytical chemistry (journal) , reaction rate constant , kinetics , catalysis , thermodynamics , chromatography , organic chemistry , physics , quantum mechanics
Study of CO poisoning of platinum and other alloy electrodes are usually carried out in aqueous electrolyte on a pre-adsorbed monolayer of CO . The effect of CO poisoning on the performance of Fuel Cells have been studies previously . However, both these techniques have their own limitations in estimating the rates of CO adsorption, desorption, and oxidation on composite electrodes. In this study, we conduct experiments on a fully assembled fuel to estimate the rates of CO adsorption, desorption and oxidation under different temperature conditions.

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