Electrochemical Determination of the Thermodynamic Properties of Lithium-Antimony Alloys | Zendy

Margaret Kane | Zendy; Jocelyn M. Newhouse | Zendy; Donald R. Sadoway | Zendy

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Electrochemical Determination of the Thermodynamic Properties of Lithium-Antimony Alloys

Author(s) -

Margaret Kane,

Jocelyn M. Newhouse,

Donald R. Sadoway

Publication year - 2014

Publication title -

journal of the electrochemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.258

H-Index - 271

eISSN - 1945-7111

pISSN - 0013-4651

DOI - 10.1149/2.0671503jes

Subject(s) - electromotive force , eutectic system , antimony , phase diagram , emf measurement , thermodynamics , lithium (medication) , materials science , electrochemistry , alloy , electrochemical cell , activity coefficient , electrode , phase (matter) , chemistry , metallurgy , medicine , physics , organic chemistry , endocrinology , electrolyte , quantum mechanics , aqueous solution

The variation in the high temperature thermodynamic properties of the Li-Sb system with temperature (425–775ºC) and composition (x[subscript Li] = 0.01–0.75) was determined by electromotive force (emf) measurements in a cell configured as follows: Li-Bi reference electrode (x[subscript Bi] = 0.35) | eutectic of LiCl-KCl or LiCl-LiF | Li-Sb alloy. On the basis of these data the Li-Sb couple was deemed attractive for storage of electrical energy in a liquid metal battery. In addition, an updated Li-Sb binary phase diagram is proposed.TOTAL (Firm)Massachusetts Institute of Technology. John Reed Undergraduate Research Opportunities Program Fun

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