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Biophotovoltaic devices modified with immobilized polymeric osmium/azine redox-mediators exhibited a considerable electrical output enhancement (64/43-fold under light/dark conditions, respectively). More importantly, the systems exhibited uninterrupted current generation at same magnitude levels during day/night cycles, paving the way toward solar energy conversion bio-panels that will not require energy storage peripherals

Redox-Polymers Enable Uninterrupted Day/Night Photo-Driven Electricity Generation in Biophotovoltaic Devices