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Ordered anodic porous alumina with large-scale periodicity was fabricated via phosphonoacetic acid anodizing. Aluminum specimens were anodized in a 0.1–0.9 M phosphonoacetic acid solution under various electrochemical operating conditions, and optimum anodizing at 205–225 V exhibited self-ordering growth of the porous alumina. These self-ordering voltages during phosphonoacetic acid anodizing filled an undiscovered vacant region in the linear relationship between the self-ordering voltage and the cell diameter. The nanostructured aluminum surface formed via self-ordering phosphonoacetic acid anodizing produced a bright structural coloration with a visible light wavelength of 500–700 nm, which is useful for optical nanoapplications

Self-Ordered Aluminum Anodizing in Phosphonoacetic Acid and Its Structural Coloration