Nickel Based Anodes of Single Chamber Solid Oxide Fuel Cells: A Catalytic Study
Author(s) -
Geoffroy Gadacz,
Sorina Udroiu,
Jean-Paul Viricelle,
Christophe Pijolat,
Michèle Pijolat
Publication year - 2009
Publication title -
ecs transactions
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.235
H-Index - 52
eISSN - 1938-6737
pISSN - 1938-5862
DOI - 10.1149/1.3242369
Subject(s) - nickel , cermet , propane , materials science , catalysis , anode , oxygen , oxide , metal , hydrocarbon , solid oxide fuel cell , nickel oxide , chemical engineering , inorganic chemistry , metallurgy , electrode , chemistry , organic chemistry , ceramic , engineering
International audienceSingle chamber solid oxide fuel cells (SCFC) are an alternative concept to traditional SOFC's. Conventional anodes, which consist of a cermet of metallic Ni and ionic conductor, have to work under a mixture of hydrocarbon and oxygen. This paper presents a catalytic study of C3H8 oxidation by Ce0.9Gd0.1O1.95 and nickel. The influence of temperature and oxygen to propane ratio on the nickel oxidation state are clarified thanks to catalytic tests and electrical conductivity measurements. The results show that the temperature must be higher than a critical value in order to maintain the nickel particles in the metallic state. Furthermore, at high temperature, the conversion of the initial mixture leads to the water-gas-shift equilibrium
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