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A Method to Separate Process Contributions in Impedance Spectra by Variation of Test Conditions
Author(s) -
Søren Højgaard Jensen,
Anne Hauch,
Peter Vang Hendriksen,
Mogens Bjerg Mogensen,
Nikolaos Bonanos,
Torben Jacobsen
Publication year - 2007
Publication title -
journal of the electrochemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.258
H-Index - 271
eISSN - 1945-7111
pISSN - 0013-4651
DOI - 10.1149/1.2790791
Subject(s) - electrical impedance , cathode , anode , dielectric spectroscopy , materials science , analytical chemistry (journal) , electrochemistry , oxide , chemistry , electrode , electrical engineering , engineering , chromatography , metallurgy
Many processes contribute to the overall impedance of an electrochemical cell, and these may be difficult to separate in the impedance spectrum. Here, we present an investigation of a solid oxide fuel cell based on differences in impedance spectra due to a change of operating parameters and present the result as the derivative of the impedance with respect to ln(f). The method is used to separate the anode and cathode contributions and to identify various types of processes.

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