Some Studies on a Solid‐State Sulfur Probe for Coal Gasification Systems | Zendy

Κ. T. Jacob | Zendy; D. Bhogeswara Rao | Zendy; H. G. Nelson | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

Some Studies on a Solid‐State Sulfur Probe for Coal Gasification Systems

Author(s) -

Κ. T. Jacob,

D. Bhogeswara Rao,

H. G. Nelson

Publication year - 1978

Publication title -

journal of the electrochemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.258

H-Index - 271

eISSN - 1945-7111

pISSN - 0013-4651

DOI - 10.1149/1.2131543

Subject(s) - sulfur , nernst equation , fluoride , chemistry , sulfide , calcium oxide , fluorine , electrolyte , inorganic chemistry , calcium , coal , solid oxide fuel cell , coal gasification , electrode , mineralogy , organic chemistry

Measurements on the solid electrolyte cell (Ar + H/sub 2/ + H/sub 2/S/CaS + CaF/sub 2/ + (Pt)//CaF/sub 2///(Pt) + CaF/sub 2/ + CaS/H/sub 2/ + H/sub 2/+Ar) show that the emf of the cell is directly related to the difference in sulfur potentials established at the Ar + H/sub 2/ + H/sub 2/S/electrode interfaces. The electrodes convert the sulfur potential gradient across the calcium fluoride electrolyte into an equivalent fluorine potential gradient. Response time of the probe varies from approximately 9 hr at 990/sup 0/K to 2.5 hr at 1225/sup 0/K. The conversion of calcium sulfide and/or calcium fluoride into calcium oxide is not a problem anticipated in commercial coal gasification systems. Suggestions are presented for improving the cell for such commercial applications.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research