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Control of Volume Resistivity in Inorganic‐Organic Separators
Author(s) -
D. W. Sheibley,
Michelle A. Manzo
Publication year - 1980
Publication title -
journal of the electrochemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.258
H-Index - 271
eISSN - 1945-7111
pISSN - 0013-4651
DOI - 10.1149/1.2129473
Subject(s) - microporous material , coating , separator (oil production) , materials science , electrical resistivity and conductivity , chemical engineering , filler (materials) , composite material , plasticizer , polymer , mineralogy , chemistry , physics , electrical engineering , thermodynamics , engineering
Control of resistivity in NASA inorganic-organic separators is achieved by incorporating small percentages of high surface area, fine particle silica with other ingredients in the separator coating. The volume resistivity is predictable from the surface area of filler particles in the coating. The approach is applied to two polymer- plasticizer -filler coating systems, where the filler content of each is below the generally acknowledged critical pigment volume concentration of the coating. Application of these coating systems to 0.0254 cm thick (10-mil) fuel cell grade asbestos sheet produces inexpensive, flexible, microporous separators that perform as well as the original inorganic-organic concept, the Astropower separator.

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