Studies on the Acid‐Base Properties of the AlBr3 ‐ NaBr Melts | Zendy

Hidetaka Hayashi | Zendy; Nobuyuki Hayashi | Zendy; Z. Takehara | Zendy; Akiyoshi Katagiri | Zendy

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Studies on the Acid‐Base Properties of the AlBr3 ‐ NaBr Melts

Author(s) -

Hidetaka Hayashi,

Nobuyuki Hayashi,

Z. Takehara,

Akiyoshi Katagiri

Publication year - 1989

Publication title -

journal of the electrochemical society

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.258

H-Index - 271

eISSN - 1945-7111

pISSN - 0013-4651

DOI - 10.1149/1.2097508

Subject(s) - chemistry , electromotive force , base (topology) , zinc , equilibrium constant , inorganic chemistry , analytical chemistry (journal) , acid–base reaction , thermodynamics , organic chemistry , mathematical analysis , mathematics , physics , quantum mechanics

The acid-base properties of the ZnBr[2]-NaBr melts at 623 K were investigated on the basis of the electromotive force measurements of a zinc-zinc concentration cell. The following two chemical equilibria were postulated to describe the acid-base character of the melts ZBnr[2]+Br[-]=ZnBr[3][-] K[1] ZnBr[3][-]+Br[-] =ZnBr[4][2+] K[2] The equilibrium constants K[1] and K[2], were determined to be 5.0×10, and 1.0×10[2], respectively, at 623 K

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