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A Simple Model for a Zinc/Bromine Flow Cell and Associated Storage Tanks
Author(s) -
Greg Simpson,
Ralph E. White
Publication year - 1990
Publication title -
journal of the electrochemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.258
H-Index - 271
eISSN - 1945-7111
pISSN - 0013-4651
DOI - 10.1149/1.2086813
Subject(s) - bromine , zinc , bromide , zinc bromide , chemistry , flow (mathematics) , residence time (fluid dynamics) , homogeneous , storage tank , battery (electricity) , flow battery , thermodynamics , inorganic chemistry , mechanics , engineering , waste management , physics , organic chemistry , power (physics) , geotechnical engineering
A simple model for a parallel plate, zinc/bromine flow cell and associated storage tanks is presented and used to make time-dependent predictions for various quantities in the system. The model is based on a previously published algebraic model of the cell at steady-state and time-dependent, first-order differential equations for the storage tanks. The Butler--Volmer equation is used for the electrochemical reactions, and the homogeneous reaction between bromine and bromide is included. The model predictions indicate that the charging operation of a zinc/bromine battery can be significantly improved by using a storage tank with a larger residence time for the bromine side of the system.

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