Inhibition of AA2024-T3 on a Phase-by-Phase Basis Using an Environmentally Benign Inhibitor, Cerium Dibutyl Phosphate | Zendy

N. Birbilis | Zendy; R. G. Buchheit | Zendy; Derek Ho | Zendy; Maria Forsyth | Zendy

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Inhibition of AA2024-T3 on a Phase-by-Phase Basis Using an Environmentally Benign Inhibitor, Cerium Dibutyl Phosphate

Author(s) -

N. Birbilis,

R. G. Buchheit,

Derek Ho,

Maria Forsyth

Publication year - 2005

Publication title -

electrochemical and solid-state letters

Language(s) - English

Resource type - Journals

eISSN - 1944-8775

pISSN - 1099-0062

DOI - 10.1149/1.2073672

Subject(s) - intermetallic , cerium , materials science , polarization (electrochemistry) , alloy , anode , inorganic chemistry , phosphate , dissolution , corrosion , chloride , oxygen , nuclear chemistry , metallurgy , chemistry , organic chemistry , electrode

the oxygen reduction reaction. 8,9,18 Therefore, in this work, we investigated the effectiveness of Cedbp3 as both an anodic and cathodic inhibitor on intermetallic compounds present as particles in 2024-T3, with the aim of characterizing electrochemically the mechanism of inhibitor action, while adopting a novel approach to achieve this. Ultimately, the inhibitor must reveal mixed properties to approach the inhibition efficiency of chromates. We suggest that Cedbp3 representing an optimized inhibitor of the Ce-based family, based on chemical considerations, will serve as good environmentally benign corrosion inhibitor for AA2024-T3.

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