Evidence of Mn Occupation of Ga Site in Ferromagnetic (Ga, Mn)N Semiconductor Observed by EXAFS
Author(s) -
Jeong Min Baik,
Sanguk Kim,
Yang Mo Koo,
Tae Won Kang,
JongLam Lee
Publication year - 2004
Publication title -
electrochemical and solid-state letters
Language(s) - English
Resource type - Journals
eISSN - 1944-8775
pISSN - 1099-0062
DOI - 10.1149/1.1813365
Subject(s) - extended x ray absorption fine structure , ferromagnetism , materials science , magnetic semiconductor , impurity , ion , semiconductor , manganese , absorption (acoustics) , crystallography , analytical chemistry (journal) , absorption spectroscopy , condensed matter physics , chemistry , metallurgy , optoelectronics , optics , physics , organic chemistry , chromatography , composite material
The local structure of Mn impurities in a ferromagnetic (Ga, Mn)N semiconductor was investigated using extended X-ray absorption fine structure (EXAFS). The ferromagnetic signal increased and maintained up to room temperature as N ions were implanted into Mn-implanted GaN. The X-ray results showed that Mn ions occupied Ga sites to form (Ga, Mn) N semiconductor. The Mn concentration occupying Ga sites increased from 2.5 to 3.8% and the formation of Mn-N compounds such as Mn6N2.58 and Mn3N2 was prohibited by implanting N atoms. As a result, the N-vacancies reduced and net hole concentration increased, resulting in the enhancement of ferromagnetic property.close2
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