The Study of Cerium Tetrafluoride Vaporization by Knudsen Effusion Mass Spectrometry | Zendy

N.S. Chilingarov | Zendy; Igor M. Shlyapnikov | Zendy; Zoran Mazej | Zendy; Alexander E. Moiseev | Zendy; Yuri M. Shlyapnikov | Zendy; I. V. Ishtubaev | Zendy

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The Study of Cerium Tetrafluoride Vaporization by Knudsen Effusion Mass Spectrometry

Author(s) -

N.S. Chilingarov,

Igor M. Shlyapnikov,

Zoran Mazej,

Alexander E. Moiseev,

Yuri M. Shlyapnikov,

I. V. Ishtubaev

Publication year - 2013

Publication title -

ecs transactions

Language(s) - English

Resource type - Journals

eISSN - 1938-6737

pISSN - 1938-5862

DOI - 10.1149/04601.0191ecst

Subject(s) - vaporization , tetrafluoride , sublimation (psychology) , knudsen number , chemistry , mass spectrometry , vapor pressure , isothermal process , evaporation , thermodynamics , knudsen flow , effusion , enthalpy , analytical chemistry (journal) , chromatography , organic chemistry , psychology , physics , psychotherapist

The evaporation and decomposition of cerium tetrafluoride CeF 4 (s) at high temperatures were studied by means of Knudsen Effusion Mass Spectrometry (KEMS). The saturated vapor pressure over CeF 4 (s) was determined by the isothermal evaporation of the sample from Pt Knudsen cell. The enthalpy of CeF 4 (s) sublimation was calculated using the second and the third laws of thermodynamics.

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