Interplay among Spin, Orbital and Lattice Degrees of Freedom int2gElectron Systems with Edge-Sharing Network of Octahedra
Author(s) -
Yukitoshi Motome,
Hirokazu Tsunetsugu,
Toshiya Hikihara,
Nic Shan,
Karlo Penc
Publication year - 2005
Publication title -
progress of theoretical physics supplement
Language(s) - English
Resource type - Journals
ISSN - 0375-9687
DOI - 10.1143/ptps.159.314
Subject(s) - octahedron , lattice (music) , condensed matter physics , electron , degrees of freedom (physics and chemistry) , enhanced data rates for gsm evolution , physics , spin (aerodynamics) , crystallography , crystal structure , chemistry , quantum mechanics , computer science , telecommunications , thermodynamics , acoustics
Transition metal oxides whose lattice structure has edge-sharing network ofoctahedra constitute a diverse group of intriguing materials besides compoundswith corner-sharing octahedra such as perovskites. We present a theoreticalinvestigation of the interplay among spin, orbital and lattice degrees offreedom in these materials. We focus on $t_{2g}$ electron systems where a keencompetition among those degrees of freedom is expected to emerge under arelatively weak Jahn-Teller coupling. We study the interplay between spin andorbital degrees of freedom in vanadium spinels and titanium pyroxenes. Weclarify the important role of the strong anisotropy in the orbital interactionsdue to the edge-sharing geometry. We also discuss the interplay between spinand lattice in chromium spinels focusing on the magnetization process under theexternal magnetic field.Comment: 5 pages, 2 figures, proceedings submitted to QSS0
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