Effective Electron-Electron Interaction in Organic Chain Molecules
Author(s) -
Junichi Yoshida,
Kiyoshi Nishikawa,
Shigeyuki Aono
Publication year - 1973
Publication title -
progress of theoretical physics
Language(s) - English
Resource type - Journals
eISSN - 1347-4081
pISSN - 0033-068X
DOI - 10.1143/ptp.50.830
Subject(s) - physics , electron , molecule , electron transport chain , organic molecules , chain (unit) , electron pair , chemical physics , molecular physics , quantum mechanics , chemistry , biochemistry
Effective electron-electron interactions are investigated in chain molecules with substituents. The 'system under consideration is divided into two parts: the main chain called the spine and the substituents which are side chains in our case. In estimating the effective electron electron interaction in the spine, the polarization effects arising from the spine and the side chains are both taken into account. The resultant formula, thus, is rather general, so that the current treatments are reproduced as special ones. A few examples are treated numerical,ly. Results indicate that Little's idea, namely the room temperature organic superconductor is unlikely from the viewpoint of the effective interaction.
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