Microscopic Dielectric Constant in Insulators
Author(s) -
Yositaka Onodera
Publication year - 1973
Publication title -
progress of theoretical physics
Language(s) - English
Resource type - Journals
eISSN - 1347-4081
pISSN - 0033-068X
DOI - 10.1143/ptp.49.37
Subject(s) - physics , dielectric , electron , polarization (electrochemistry) , lorentz transformation , condensed matter physics , constant (computer programming) , quantum electrodynamics , quantum mechanics , chemistry , computer science , programming language
A conventional expression for the microscopic dielectric constant as obtained by Adler and Wiser in the Hartree approximation lacks the self-polarization correction arising from the polarization of electrons by its own field and hence is invalid for tightly bound electrons. When the correction is introduced, the microscopic dielectric constant can still be expressed in terms of a simple formula. With the use of the "separable" approximation to the polarization, which holds well for tightly bound electrons, the result is shown to recapture the Lorentz-Lorenz formula for the macroscopic dielectric constant in the limit of completely localized electrons.
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