A General Theory of Diffusion
Author(s) -
Liqiu Wang
Publication year - 1999
Publication title -
progress of theoretical physics
Language(s) - English
Resource type - Journals
eISSN - 1347-4081
pISSN - 0033-068X
DOI - 10.1143/ptp.101.541
Subject(s) - physics , thermal conduction , diffusion , momentum diffusion , momentum (technical analysis) , heat flux , diffusion process , mass flux , viscosity , general theory , fourier transform , classical mechanics , flux (metallurgy) , statistical physics , thermodynamics , theoretical physics , heat transfer , quantum mechanics , knowledge management , innovation diffusion , finance , computer science , turbulence , economics , materials science , metallurgy
Both necessary and sufficient conditions are derived in a systematic, rigorous way for a diffusion process to satisfy two fundamental principles: the principle of frame-indifference and the second law of thermodynamics. This yields a general theory of diffusion which generalizes the classical flux laws (Newton's law of viscosity for momentum, Fourier's law of heat conduction for heat, and Fick's first law of diffusion for mass) in the sense that it can be used in a diffusion process with the effect of convection. Also developed is an approximate theory which reduces three flux functions in the general theory to three material-coefficients.link_to_OA_fulltex
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