A facile synthesis of metalla- octafluorocyclopentane complexes of ruthenium and nickel | Zendy

Waltraud Gasafi-Martin | Zendy; Gabriele Oberendfellner | Zendy; Konrad Von Werner | Zendy

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A facile synthesis of metalla- octafluorocyclopentane complexes of ruthenium and nickel

Author(s) -

Waltraud Gasafi-Martin,

Gabriele Oberendfellner,

Konrad Von Werner

Publication year - 1996

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v96-217

Subject(s) - chemistry , ruthenium , hydrogenolysis , phosphine , nickel , hydride , medicinal chemistry , tetrafluoroethylene , triphenylphosphine , sodium hydride , hydrogen , sodium , polymer chemistry , organic chemistry , catalysis , polymer , copolymer

Reduction of the dihalogeno complexes RuCl 2 (PPh 3 ) 4 and NiBr 2 L 2 (L = tertiary phosphine) with sodium hydride in MeCN in the presence of tetrafluoroethylene gives complexes containing five-membered MC 4 F 8 rings. 1,2-Dihydrotetrafluoroethane is a by-product of these syntheses, especially when hydrogen is added. The M—C bonds of the metalla-perfluorocyclopentane complexes are remarkably stable against hydrogenolysis. Key words: metalla-octafluorocyclopentanes of ruthenium(II) and nickel(II).

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