Nucleic acid related compounds. 63. Synthesis of 5′-deoxy-5′-methyleneadenosine and related Wittig-extended nucleosides | Zendy

Stanislaw F. Wnuk | Zendy; Morris J. Robins | Zendy

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Nucleic acid related compounds. 63. Synthesis of 5′-deoxy-5′-methyleneadenosine and related Wittig-extended nucleosides

Author(s) -

Stanislaw F. Wnuk,

Morris J. Robins

Publication year - 1991

Publication title -

canadian journal of chemistry

Language(s) - French

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v91-051

Subject(s) - chemistry , tosyl , wittig reaction , aldehyde , allylic rearrangement , deoxyadenosine , isomerization , cleavage (geology) , stereochemistry , nucleic acid , medicinal chemistry , organic chemistry , adenosine , biochemistry , geotechnical engineering , fracture (geology) , engineering , catalysis

l'aide d'arnmoniac et d'acide, conduit la 9-(5,6-didesoxy-P-D- ribo-hex-5-Cnofuranosy1)adCnine (5'-dksoxy-5'-m6thylbneadCnosine) (4). L'oxydation de la ou de la 2',3'-0-isopropylidbne- adtnosine (lb)), suivie d'une rtaction des 5'-aldehydes bruts (2a ou 26) avec le

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