Direct synthesis of indenones from alkenyliron complexes
Author(s) -
Ian R. Butler,
Joanne E. Elliott,
Jean Houde
Publication year - 1989
Publication title -
canadian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.323
H-Index - 68
eISSN - 1480-3291
pISSN - 0008-4042
DOI - 10.1139/v89-201
Subject(s) - chemistry , metathesis , thermal decomposition , cyclopentadienyl complex , combinatorial chemistry , aryl , salt metathesis reaction , decomposition , product (mathematics) , medicinal chemistry , organic chemistry , catalysis , polymerization , polymer , alkyl , geometry , mathematics
Alkenyliron complexes have been prepared by the metathesis of dicarbonyl(η 5 -cyclopentadienyl)iodoiron with aryl-substituted alkenyllithiums. Thermolysis of the product alkenyliron complexes leads to the formation of indenones in good yields. Keywords: alkenyliron, carbonyl, indenone, insertion, metallation, synthesis.
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