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This research was made possible by the generous financial support of the Comision Asesora de Investigacion Cientifica y Tecnica (project number PB85-0335). Maria P. Bueno would like to express her gratitude to the Diputacion General de Aragon and Paula Charro to the Instituto de Estudios Riojanos for a grant.

Natural amino acids as chiral auxiliaries in asymmetric Diels–Alder reactions