Molecular emission and electronic structure of associated chlorophyll a | Zendy

N. E. Binnie | Zendy; L. V. Haley | Zendy; Tony A. Mattioli | Zendy; D. L. Thibodeau | Zendy; W. Wang | Zendy; J. A. Koningstein | Zendy

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Molecular emission and electronic structure of associated chlorophyll a

Author(s) -

N. E. Binnie,

L. V. Haley,

Tony A. Mattioli,

D. L. Thibodeau,

W. Wang,

J. A. Koningstein

Publication year - 1988

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v88-279

Subject(s) - chemistry , chlorophyll , raman spectroscopy , chlorophyll a , fluorescence , monomer , exciton , excitation , wavelength , excitation wavelength , emission spectrum , luminescence , analytical chemistry (journal) , photochemistry , diagram , spectral line , optoelectronics , optics , organic chemistry , polymer , materials science , biochemistry , physics , electrical engineering , statistics , mathematics , quantum mechanics , astronomy , engineering

We report the wavelength-selective Raman and fluorescence spectra of monomeric and aggregate species of chlorophyll a in solution. The excitation profile for the molecular emission of the various chlorophyll complexes permit the construction of part of the electronic energy level diagram. For a T-shaped dimeric chlorophyll a, pseudo-exciton splittings of 667 cm −1 in the Soret and 397 cm −1 in the Q y bands are obtained.

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