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The structure of traversianal, a tricyclic diterpenoid fungal metabolite of Cercospora traversiana, has been elucidated through detailed  1 H and  13 C magnetic resonance studies, including homo- and heteronuclear correlation spectra of the natural product and examination of  13 C-labelled material obtained by [1,2- 13 C 2 ]acetate incorporation experiments. Its stereochemistry was established from a series of nuclear Overhauser effect difference spectra. The tricyclic carbon skeleton of traversianal is that of the fusicoccin/cotylenin and ophiobolane terpenes although the oxygenation pattern closely resembles the latter. Incorporation experiments with [2,2,2- 2 H 3 , 1- 13 C 1 ]acetate revealed that traversianal arises by a sequence that differs substantially from that established for the fusicoccanes but rather resembles that previously shown for the ophiobolanes, in the retention of hydride at C-2, -10, and -14. However, the opposite configuration of the methyl group at C-3 suggests that the route to traversianal involves a terminal trans-geranylgeranyl unit instead of the cis unit implicated in ophiobolin generation.

canadian journal of chemistry

The structure, stereochemistry, and biosynthetic origin of a diterpenoid fungal metabolite, traversianal, established by 1H, 2H, and 13C magnetic resonance