Organometallic aspects of cytochrome P-450 metabolism
Author(s) -
Junichiro Setsune,
David Dolphin
Publication year - 1987
Publication title -
canadian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.323
H-Index - 68
eISSN - 1480-3291
pISSN - 0008-4042
DOI - 10.1139/v87-080
Subject(s) - chemistry , ruthenium , organometallic chemistry , redox , cobalt , cytochrome , porphyrin , group 2 organometallic chemistry , oxidation reduction , organic chemistry , stereochemistry , photochemistry , catalysis , biochemistry , molecule , enzyme
Carbeneiron porphyrins, (N,Fe)-bridged methyleneiron porphyrins, N-alkyliron porphyrins and σ-alkyliron porphyrins have all been shown to occur in nature and to be interconvertible via redox reactions. The chemistry of the naturally occurring iron porphyrins and model iron, cobalt, and ruthenium porphyrins is reviewed emphasizing their organometallic chemistry.
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