Total synthesis of a proposed structure of isohimachalone | Zendy

HsingJang Liu | Zendy; E. N. C. BROWNE | Zendy

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Total synthesis of a proposed structure of isohimachalone

Author(s) -

HsingJang Liu,

E. N. C. BROWNE

Publication year - 1987

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v87-028

Subject(s) - chemistry , sesquiterpene , ketone , natural product , total synthesis , natural materials , stereochemistry , organic chemistry , group (periodic table) , computational chemistry , polymer science

A proposed structure 5 of the naturally occurring sesquiterpene ketone isohimachalone has been synthesized by a route using the unique Diels–Alder chemistry developed in our laboratory. The product has been shown to be non-identical with the natural material by comparison of spectral data, a result which has been implied by the work of an independent group using direct methods. Spectroscopic differences between our synthetic material and the natural and closely related products are discussed.

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