Open AccessL'o-nitrobenzylidènediméthylsulfuranne: synthèse, réactivité
Author(s) -
Yannick Le Stanc,
M. Le Corre
Publication year - 1985
Publication title -
canadian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.323
H-Index - 68
eISSN - 1480-3291
pISSN - 0008-4042
DOI - 10.1139/v85-490
Subject(s) - chemistry , dichloromethane , aqueous solution , bromide , sodium hydroxide , medicinal chemistry , alcohol , sulfide , organic chemistry , solvent
In aqueous solution, o-nitrobenzyldimethylsulfonium bromide and the corresponding ylid give, depending upon the conditions, o-nitrobenzyl alcohol, o-nitrobenzylsulfide, or methyl o-hydroxymethylbenzyl sulfide. The o-nitrophenyloxiranes may be obtained by the reaction of nitrobenzylidenedimethylsulfurane with aldehydes in a two-phase aqueous sodium hydroxide/dichloromethane system.
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