Interaction entre le groupe carbonyle et les hétéroatomes des acétates d'éthyle α-substitués | Zendy

Georges Guihéneuf | Zendy; CHRISTIAN BENARD | Zendy; Abdeljalil Lachkar | Zendy; Maryvonne Luçon | Zendy

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Interaction entre le groupe carbonyle et les hétéroatomes des acétates d'éthyle α-substitués

Author(s) -

Georges Guihéneuf,

CHRISTIAN BENARD,

Abdeljalil Lachkar,

Maryvonne Luçon

Publication year - 1985

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v85-388

Subject(s) - chemistry , lone pair , nitrogen , conformational isomerism , solvent , spectral line , carbonyl group , medicinal chemistry , stereochemistry , molecule , organic chemistry , physics , astronomy

Infrared spectra of ethyl α-aminoacetates show three bands in the carbonyl region. Solvent effects show that this is not due to Fermi resonance. These spectra can be interpreted using a model that considers the interactions between the nitrogen lone pair and the carbonyl group. The existence of an equilibrium between the conformers caused by the different orientations of the nitrogen lone pair with respect to the carbonyl group can be forecast. This model enables the interpretation of the carbonyl absorptions of the α-substituted (methoxy and ethoxy) ethyl acetates.

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