The effects of selected gases upon ethanol: hydrogen bond breaking by O2 and N2
Author(s) -
T. L. Mathers,
G. Schoeffler,
S. P. McGlynn
Publication year - 1985
Publication title -
canadian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.323
H-Index - 68
eISSN - 1480-3291
pISSN - 0008-4042
DOI - 10.1139/v85-309
Subject(s) - chemistry , phosphorescence , hydrogen , molecule , hydrogen bond , alcohol , ethanol , luminescence , photochemistry , organic chemistry , physics , optoelectronics , quantum mechanics , fluorescence
The temperature dependency of the phosphorescence properties of aromatic hydrocarbons in alcoholic glasses exhibits a number of phenomena that have not been described previously. Chief among these are the effects of added gases (O 2 , N 2 , C 2 H 6 , Ar), some of which produce major changes in the luminescence characteristics. These are discussed, and rationalized in terms of a model which presumes that O 2 and N 2 can disrupt the normal hydrogen bonding process between alcohol molecules.
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