Electrochemical reduction of quinoxalino[2,3-b]quinoxaline: a revised mechanism | Zendy

Joseph Armand | Zendy; Line Boulares | Zendy; Christian Bellec | Zendy; Claudette Bois | Zendy; M. PHILOCHELEVISALLES | Zendy; Jean Pinson | Zendy

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Electrochemical reduction of quinoxalino[2,3-b]quinoxaline: a revised mechanism

Author(s) -

Joseph Armand,

Line Boulares,

Christian Bellec,

Claudette Bois,

M. PHILOCHELEVISALLES,

Jean Pinson

Publication year - 1984

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v84-170

Subject(s) - chemistry , quinoxaline , electrochemistry , benzimidazole , reduction (mathematics) , derivative (finance) , diacetyl , combinatorial chemistry , mechanism (biology) , stereochemistry , medicinal chemistry , organic chemistry , electrode , epistemology , philosophy , geometry , mathematics , financial economics , economics

The electrochemical reduction of fluoflavine 2 gives compound 9 to which we had previously assigned a hexahydroquinoxalino[2,3-b]quinoxaline structure. A crystallographic study of a diacetylated derivative of 9 shows that 9 is in fact 2-(o-aminoanilinomethyl)benzimidazole. This result permits us to propose a detailed reduction mechanism for 2 and its diacetyl derivative 25.

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