The regiospecific phase transfer catalyzed reductive carbonylation of azadienes | Zendy

Howard Alper | Zendy; Shiyamalie Amaratunga | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Open Access

The regiospecific phase transfer catalyzed reductive carbonylation of azadienes

Author(s) -

Howard Alper,

Shiyamalie Amaratunga

Publication year - 1983

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v83-232

Subject(s) - chemistry , carbonylation , catalysis , carbon monoxide , allylic rearrangement , benzene , methyl iodide , iodide , chloride , cobalt , photochemistry , medicinal chemistry , organic chemistry

Reaction of an azadiene with cobalt carbonyl, carbon monoxide, and methyl iodide under phase transfer catalysis conditions (benzene, water or aqueous NaOH, benzyltriethylammonium chloride) affords allylic amides in reasonable yields. This regiospecific reaction is sensitive to the concentration of base. One can also effect this transformation using acidic catalysis. A mechanism is proposed for the reductive carbonylation reaction.

The content you want is available to Zendy users.

Already have an account? Click here to sign in.

Having issues? You can contact us here

Accelerating Research