Kinetics of the intermolecular exchange reaction Cp3UIII–Cp3UIVCl | Zendy

M. Burton | Zendy; G. Folcher | Zendy; H. Marquet-Ellis | Zendy; Paul Rigny | Zendy; C. Giannotti | Zendy

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Kinetics of the intermolecular exchange reaction Cp₃U^III–Cp₃U^IVCl

Author(s) -

M. Burton,

G. Folcher,

H. Marquet-Ellis,

Paul Rigny,

C. Giannotti

Publication year - 1982

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v82-356

Subject(s) - chemistry , intermolecular force , kinetics , cyclopentadienyl complex , actinide , chlorine , chemical kinetics , lability , reaction mechanism , chlorine atom , electron transfer , kinetic energy , inorganic chemistry , medicinal chemistry , catalysis , molecule , organic chemistry , physics , quantum mechanics

The intermolecular exchange of cyclopentadienyl groups in the system UCp 3 –UCp 3 Cl in THF solution between 170–300 K was investigated by 1 H nmr. The kinetic results show a bimolecular mechanism and suggest an electron transfer via the chlorine atom. This first example of a symmetrical exchange in the U III –U IV system illustrates the lability of actinide organometallic compounds.

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