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The reactions of IOF 5  with SbF 5  and with AsF 5  have been investigated at low temperature by  19 F nmr and Raman spectroscopy. It was found that SbF 5  forms labile 1:1 and 2:1 complexes whereas AsF 5  forms only a 1:1 complex. The IOF 5  is bound through its oxygen atom to the Lewis acids AsF 5 , SbF 5 , or (SbF 5 ) 2 .

canadian journal of chemistry

A <sup>19</sup>F nuclear magnetic resonance and Raman spectroscopic investigation of the reaction of iodine oxide pentafluoride with the Lewis acids, antimony and arsenic pentafluoride

A 19F nuclear magnetic resonance and Raman spectroscopic investigation of the reaction of iodine oxide pentafluoride with the Lewis acids, antimony and arsenic pentafluoride

A ¹⁹F nuclear magnetic resonance and Raman spectroscopic investigation of the reaction of iodine oxide pentafluoride with the Lewis acids, antimony and arsenic pentafluoride