Open AccessConformational analysis of substituted 1,2-oxathiane 2-oxides by 13C and 1H nuclear magnetic resonance spectroscopy
Author(s) -
G. W. Buchanan,
Nagendra K. Sharma,
F. De ReinachHirtzbach,
Tony Durst
Publication year - 1977
Publication title -
canadian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.323
H-Index - 68
eISSN - 1480-3291
pISSN - 0008-4042
DOI - 10.1139/v77-008
Subject(s) - chemistry , steric effects , nuclear magnetic resonance spectroscopy , molecule , crystallography , spectroscopy , resonance (particle physics) , nuclear magnetic resonance , oxide , stereochemistry , organic chemistry , physics , particle physics , quantum mechanics
1 H and 13 C nmr results for 1,2-oxathiane 2-oxide and eight derivatives are reported. It is concluded that these molecules have a high preference for chair forms with axial S=O groups, even when a sterically bulky group such as phenyl is substituted in a syn-axial orientation to the exocyclic oxygen.