Association and hydration of alcohols in low-dielectric solvents. II. tert-Butyl alcohol and cyclohexanol
Author(s) -
Jitka Kirchnerová,
G. C. B. Cave
Publication year - 1976
Publication title -
canadian journal of chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.323
H-Index - 68
eISSN - 1480-3291
pISSN - 0008-4042
DOI - 10.1139/v76-564
Subject(s) - chemistry , chlorobenzene , cyclohexanol , benzene , cyclohexane , alcohol , xylene , carbon tetrachloride , organic chemistry , dielectric , dichlorobenzene , solvent , inorganic chemistry , medicinal chemistry , catalysis , physics , optoelectronics
Formulae and thermodynamic formation constants of the aggregates of tert-butyl alcohol and of cyclohexanol and their hydrates in six low-dielectric solvents have been deduced by using an iterative mathematical treatment of distribution and isopiestic data. The solvents were cyclohexane, carbon tetrachloride, p-xylene, benzene, chlorobenzene, and o-dichlorobenzene. These results and those previously obtained for n-butanol in the same six solvents are discussed in a qualitative way.
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