Excess volume and viscosity of binary liquid acid–base mixtures | Zendy

Horácio N. Sólimo | Zendy; Roque Riggio | Zendy; José Antônio Azevedo Espíndola | Zendy; S. Alonso | Zendy; Miguel Katz | Zendy

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Excess volume and viscosity of binary liquid acid–base mixtures

Author(s) -

Horácio N. Sólimo,

Roque Riggio,

José Antônio Azevedo Espíndola,

S. Alonso,

Miguel Katz

Publication year - 1976

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v76-446

Subject(s) - chemistry , aniline , molar volume , viscosity , volume (thermodynamics) , dimethylaniline , pyridine , thermodynamics , base (topology) , molar , partial molar property , organic chemistry , aqueous solution , medicine , mathematical analysis , physics , mathematics , dentistry

Densities, viscosities, and refractive indices at 25 °C were determined for the systems: o chlorophenol + N,N-dimethylaniline, o-chlorophenol + aniline, o-chlorophenol + m-toluidine, and o-chlorophenol + pyridine. From the experimental results the excess volume, excess viscosity, excess molar free energy of activation of flow, and the excess partial molar volume were calculated. There is evidence of complex formation between o-chlorophenol and the four bases.

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