Préparation et étude des isothiocyanatoboranes halogènes | Zendy

J. Dazord | Zendy; H. Mongeot | Zendy; H. R. Atchekzaï | Zendy; J.-P. Tuchagues | Zendy

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Préparation et étude des isothiocyanatoboranes halogènes

Author(s) -

J. Dazord,

H. Mongeot,

H. R. Atchekzaï,

J.-P. Tuchagues

Publication year - 1976

Publication title -

canadian journal of chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.323

H-Index - 68

eISSN - 1480-3291

pISSN - 0008-4042

DOI - 10.1139/v76-306

Subject(s) - chemistry , trihalide , boron , mass spectrometry , halide , raman spectroscopy , redistribution (election) , sulfur , infrared spectroscopy , nitrogen , mass spectrum , inorganic chemistry , organic chemistry , physics , chromatography , politics , political science , law , optics

The mixed halide–pseudohalides BX n (NCS) 3−n (n = 1 or 2) have been obtained except for X = F. Mixtures of these compounds with boron trihalide and boron triisothiocyanate are prepared by the reaction of BX 3 either with metal isothiocyanates or with boron triisothiocyanate. Mass spectrometry, infrared, Raman, and 11 B nmr data are reported. Rapid redistribution reactions prevent the isolation of the mixed species. Vibration spectrometry shows that boron is bonded to the nitrogen of the NCS group and not to the sulfur.

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