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The new C 10 H 10  hydrocarbon, 2,3-dimethylenebicyclo[2.2.2]octa-5,7-diene (7), has been synthesized. Diels–Alder additions to 7 afford a useful route to annelated barrelenes.

Chemistry of Proximal π-Bond Systems. Part II. Synthesis of 2,3-Dimethylenebicyclo[2.2.2]octa-5,7-diene